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8890 



Bureau of Mines Information Circular/1982 



Analyses of Natural Gases, 1981 



By Richard D. Miller and Floyd R. Hertweck, Jr. 



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UNITED STATES DEPARTMENT OF THE INTERIOR 



Information Circular 8890 



Analyses of Natural Gases, 1981 



By Richard D. Miller and Floyd R. Hertweck, Jr. 




UNITED STATES DEPARTMENT OF THE INTERIOR 
James G. Watt, Secretary 

BUREAU OF MINES 
Robert C. Norton, Director 



As the Nation's principal conservation agency, the Department of the Interior 
has responsibility for most of our nationally owned public lands and natural 
resources. This includes fostering the wisest use of our land and water re- 
sources, protecting our fish and wildlife, preserving the environmental and 
cultural values of our national parks and historical places, and providing for 
the enjoyment of life through outdoOT recreation. The Department assesses 
our energy and mineral resources and works to assure that their development is 
in the best interests of all our people. The Department also has a major re- 
sponsibility for American Indian reservation communities and for people who 
live in Island Territories under U.S. administration. 



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This publication lias been cataloged as follows: 




Miller, Richard D 

Analyses of natural gases, 1981. 

(Information circular / United States Department of the Interior, 
Bureau of Mines ; 8890) 

Includes bibliographical references. 

Supt, of Docs, no.: I 28.27:8890. 

1. Gas, Natural— Analysis. I. Hertweck, Floyd R. II. Title. III. 
Series: Information circular (United States. Bureau of Mines) ; 8890. 



TN295.U4 {TP350] 622s [553.2'85'0287] 82-600210 



For sale by the Superintendent of Documents, U.S. Government Printing Office 

Washington, D.C. 20402 



CONTENTS 

fsj Page 

^; Introduction 1 

^ Acknowledgments 2 

Geologic provinces of the United States 2 

Tables 8 

Previous publications In this series 84 



\ 
^ 



9^ ILLUSTRATION 



^ 



1. Geologic provinces of the United States 3 

TABLES 

1. Samples from gas and oil wells In the United States 9 

2. Samples from pipelines In the United States 83 






■J 



ANALYSES OF NATURAL GASES, 1981 

By Richard D. Mi Her ^ and Floyd R. Hertweck, Jr. 2 



INTRODUCTION 

This Bureau of Mines publication contains analyses and related source 
data for 224 natural gas samples from 18 States. Of the total, 191 sam- 
ples were collected during calendar year 1981. The remaining 33 samples 
were collected during previous years, but releases granting permission 
to publish were not received until 1981. All samples were obtained and 
analyzed as part of Bureau of Mines investigations of the occurrences of 
helium in natural gases of countries with free market economies. This 
survey has been conducted since 1917. The analyses published herein 
were made by the mass spectrometer and special helium apparatus 
described previously i}^2).^ 

The results of the investigation of the occurrences of helium are pub- 
lished annually to make the information available as soon as possible to 
the gas industry and the general public. Twenty-five publications have 
presented the results of 12,827 gas analyses made prior to 1981. The 
first three bulletins 0~3^) contain analyses and related data on 
5,218 gas samples collected from 1917 through 1960; these bulletins have 
been supplemented annually by information circulars (4-17, 19-24) con- 
taining 7,609 analyses of samples collected since 1960. 

In 1976, a coiiq)ilation of the analyses made prior to 1975 was prepared 
by the Bureau of Mines and published by the National Technical Informa- 
tion Service of the U.S. Department of Commerce (18). This compilation 
contains 10,562 analyses of gas samples from oil and gas wells and natu- 
ral gas pipelines in 37 States and 23 foreign countries. In 1982, a 
conqpilation of analyses made prior to 1980 was published (25). The 1982 
publication contains 12,554 analyses of gas samples from oil and gas 
wells and natural gas pipelines in 39 States and 24 foreign countries. 
Including all of the analyses included in the 1976 publication. 

In addition to being included in the publications, all published anal- 
yses and related information are available on a magnetic tape file. The 
tape is available for $125 from the National Technical Information 
Service, Springfield, Va. 22161; orders should refer to Bureau of Mines 
tape PB82-121708. 

'Chief/ Section of Helium Resources Evaluation, Branch of Helium Resources/ Helium 
Field Operations/ Bureau of Mines / AmarillO/ Tex. 

^Geologist/ Section of Helium Resources Evaluation, Branch of Helium Resources. 
Helium Field Operations/ Bureau of Mines / Amarillo/ Tex. 

^Underlined numbers in parentheses refer to items in the list of previous publica- 
tions at the end of the report. 



ACKNOWLEDGMENTS 



The helium survey program is conducted 
by soliciting natural gas samples 
throughout the United States and other 
countries with free market economies. 
Without the assistance of the oil indus- 
try. State and national agencies, and 
many individuals engaged in oil and gas 
exploration and production, the helium 
survey with its present scope would be 
impossible. 



The analyses listed in the tables were 
made by the Section of Technical and Ana- 
lytical Services, Helium Field Opera- 
tions, Bureau of Mines, Amarillo, Tex. 
The list of analyses was produced through 
use of a conqjuter by the Section of Auto- 
matic Data Processing, Helium Field Oper- 
ations, Bureau of Mines, Amarillo, Tex. 



GEOLOGIC PROVINCES OF THE UNITED STATES 



The tables include geologic province 
codes so each sample source can be 
located within a specific geologic prov- 
ince as defined by the Committee on 
Statistics of Drilling of the American 
Association of Petroleum Geologists. 4 
These provinces, which are given in the 
following list and shown in figure 1, are 
delineated by political boundaries for 
convenience and for accommodation of 
data-processing equipment. Not all of 

Meyer, R. F. Geologic Provinces Code 
Map for Computer Use. AAPG Bull./ v. 54, 
No. 1, July 1970, pp. 1301-1305. 



the provinces shown are gas-producing 
areas, so many of the codes are not used 
in this publication. In offshore areas, 
only one code is used for each State 
since State or Federal ownership is not 
always known. Only one code, 972, is 
used for all wells in Alaska, both 
onshore and offshore, because of the lack 
of information on the location of wells 
in that State. 

The following list and figure 1 are 
taken from the article cited in 
footnote 4. 




a 



_o 

O 
(U 

O 



LU 

ID 
O 
Ll_ 



I' 'if ' ^ 



Sk 



Code Province 

100 New England province 

110 Adirondack uplift 

120 Atlantic Coast basin 

130 South Georgia-North Florida sedimentary province 

140 South Florida province 

150 Piedmont-Blue Ridge province 

160 Appalachian basin 

200 Warrior basin 

210 Mid-Gulf Coast basin 

220 Gulf Coast basin 

230 Arkla basin 

240 Desha basin 

250 Upper Mississippi embayment 

260 East Texas basin 

300 Cincinnati arch 

305 Michigan basin 

310 Wisconsin arch 

315 Illinois basin 

320 Sioux uplift 

3-25 Iowa shelf 

330 Lincoln anticline 

335 Forest City basin 

340 Ozark uplift 

345 Arkoma basin 

350 South Oklahoma folded belt province 

355 Chautauqua platform 

360 Anadarko basin 

365 Cherokee basin 

370 Nemaha anticline 

375 Sedgwick basin 

380 Sallna basin 

385 Central Kansas uplift 

390 Chadron arch 

395 Williston basin 

400 Ouachita tectonic belt province 

405 Kerr basin 

410 Llano uplift 

415 Strawn basin 

420 Fort Worth syncline 

425 Bend arch 

430 Permian basin 

435 Palo Duro basin 

440 Amarillo arch 

445 Sierra Grande uplift 

450 Las Animas arch 

455 Las Vegas-Raton basin 

460 Estancla basin 

465 Orogrande basin 



Code Province 

470 Pedregosa basin 

475 Basin-and-Range province 

500 Sweetgrass arch 

505 Montana folded belt province 

510 Central Montana uplift 

515 Powder River basin 

520 Big Horn basin 

525 Yellowstone province 

530 Wind River basin 

535 Green River basin 

540 Denver basin 

545 North Park basin 

550 South Park basin 

555 Eagle basin 

560 San Luis basin 

565 San Juan Mountain province 

570 Uinta uplift 

575 Uinta basin 

580 San Juan basin 

585 Paradox basin 

590 Black Mesa basin 

595 Piceance basin 

600 Northern Cascade Range — Okanagan province 

605 Eastern Columbia basin 

610 Idaho Mountains province 

615 Snake River basin 

620 Southern Oregon basin 

625 Great Basin province 

630 Wasatch uplift 

635 Plateau sedimentary province 

640 Mojave basin 

645 Salton basin 

650 Sierra Nevada province 

700 Bellingham basin 

705 Puget Sound province 

710 Western Columbia basin 

715 Klamath Mountains province 

720 Eel River basin 

725 Northern Coast Range province 

730 Sacramento basin 

735 Santa Cruz basin 

740 Coastal basins 

745 San Joaquin basin 

750 Santa Maria basin 

755 Ventura basin 

760 Los Angeles basin 

765 Capistrano basin 



Code Province 

800 Heceta Island area 

805 Keku Islands area 

810 Gulf of Alaska basin 

815 Copper River basin 

820 Cook Inlet basin 

830 Kandik province 

835 Kobuk province 

840 Koyukuk province 

845 Bristol Bay basin 

850 Bethel basin 

855 Norton basin 

860 Selawik basin 

863 Yukon Flats basin 

865 Lower Tanana basin 

867 Middle Tanana basin 

870 Upper Tanana basin 

873 Galena basin 

875 Innoko basin 

877 Minchumina basin 

880 .Holitna basin 

885 Arctic Foothills province 

890 Arctic Slope basin 

900 Maine Atlantic offshore — general 

901 Maine Atlantic offshore — State 

902 Maine Atlantic offshore — Federal 

903 New Hampshire Atlantic offshore — general 

904 New Hampshire Atlantic offshore — State 

905 New Hampshire Atlantic offshore — Federal 

906 Massachusetts Atlantic offshore — general 

907 Massachusetts Atlantic offshore — State 

908 Massachusetts Atlantic offshore — Federal 

909 Rhode Island Atlantic offshore — general 

910 Rhode Island Atlantic offshore — State 

911 Rhode Island Atlantic offshore — Federal 

912 Connecticut Atlantic offshore — general 

913 Connecticut Atlantic offshore — State 

914 Connecticut Atlantic offshore — Federal 

915 New York Atlantic offshore — general 

916 New York Atlantic offshore — State 

917 New York Atlantic offshore — Federal 

918 New Jersey Atlantic offshore — general 

919 New Jersey Atlantic offshore — State 

920 New Jersey Atlantic offshore — Federal 

921 Delaware Atlantic offshore — general 

922 Delaware Atlantic offshore — State 

923 Delaware Atlantic offshore — Federal 

924 Maryland Atlantic offshore — general 

925 Maryland Atlantic offshore — State 

926 Maryland Atlantic offshore — Federal 



Code Province 

927 Virginia Atlantic offshore — general 

928 Virginia Atlantic offshore — State 

929 Virginia Atlantic offshore — Federal 

930 North Carolina Atlantic offshore — general 

931 North Carolina Atlantic offshore — State 

932 North Carolina Atlantic offshore — Federal 

933 South Carolina Atlantic offshore — general 

934 South Carolina Atlantic offshore — State 

935 South Carolina Atlantic offshore — Federal 

936 Georgia Atlantic offshore — general 

937 Georgia Atlantic offshore — State 

938 Georgia Atlantic offshore — Federal 

939 Florida Atlantic offshore — general 

940 Florida Atlantic offshore — State 

941 Florida Atlantic offshore — Federal 

942 Florida Gulf of Mexico offshore — general 

943 Florida Gulf of Mexico offshore — State 

944 Florida Gulf of Mexico offshore — Federal 

945 Alabama Gulf of Mexico offshore — general 

946 Alabama Gulf of Mexico offshore — State 

947 Alabama Gulf of Mexico offshore — Federal 

948 Mississippi Gulf of Mexico offshore — general 

949 Mississippi Gulf of Mexico offshore — State 

950 Mississippi Gulf of Mexico offshore — Federal 

951 Louisiana Gulf of Mexico offshore — general 

952 Louisiana Gulf of Mexico offshore — State 

953 Louisiana Gulf of Mexico offshore — ^Federal 

954 Texas Gulf of Mexico offshore — general 

955 Texas Gulf of Mexico offshore — State 

956 Texas Gulf of Mexico offshore — Federal 
967 California Pacific offshore — general 

958 California Pacific offshore — State 

959 California Pacific offshore — Federal 

960 Oregon Pacific offshore — general 

961 Oregon Pacific offshore — State 

962 Oregon Pacific offshore — Federal 

963 Washington Pacific offshore — general 

964 Washington Pacific offshore — State 

965 Washington Pacific offshore — Federal 

972 Alaska Arctic offshore — general 

973 Alaska Arctic offshore — State 

974 Alaska Arctic offshore — Federal 

975 Alaska Bering Sea offshore — general 

976 Alaska Bering Sea offshore — State 

977 Alaska Bering Sea offshore — Federal 

978 Alaska Pacific offshore — general 

979 Alaska Pacific offshore — State 

980 Alaska Pacific offshore — Federal 

987 Minnesota Lake Superior offshore 

988 Wisconsin Lake Superior offshore 

989 Michigan Lake Superior offshore 

990 Indiana Lake Michigan offshore 



Code 



Province 



991 
992 
993 
994 
995 
996 
997 
998 
999 



Illinois Lake Michigan offshore 
Wisconsin Lake Michigan offshore 
Michigan Lake Michigan offshore 
Michigan Lake Huron offshore 
Michigan Lake Erie offshore 
Ohio Lake Erie offshore 
Pennsylvania Lake Erie offshore 
New York Lake Erie offshore 
New York Lake Ontario offshore 



TABLES 



The following tables include the results of analyses and related source data from 
gas samples which are divided into two groups as follows: 

Table 1. - Samples from gas and oil wells in the United States. 

Table 2. - Samples from pipelines in the United States. 

The following list indicates the sources of the samples listed in the tables: 



Source 



Number 

of 
samples 



Tables 



Source 



Number 

of 
samples 



Tables 



Alabama . . . . < 
Arkansas. . . . 
California. . 
Colorado. . . . 

Kansas , 

Louisiana. . , 
Michigan. . . , 
Mississippi. 
Montana. . . . . 



6 

12 

4 

12 

18 

15 

2 

5 

3 



1,2 



New Mexico. . . . 
North Dakota. . 

Ohio 

Oklahoma 

Oregon 

Pennsylvania. . 

Texas 

West Virginia. 
Wyoming 



15 
1 
2 

43 
3 
2 

48 
2 

31 



All components of the analyses in the tables are reported to the nearest 0.1 per- 
cent, except helium, which is reported to the nearest 0.01 percent. The word "trace" 
is used to denote quantities of helium of less than 0.005 percent and quantities of 
other components of less than 0.05 percent. 



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84 



PREVIOUS PUBLICATIONS IN THIS SERIES 



1. Anderson, C. C, and H, H. Hinson. 
Helium-Bearing Natural Gases of the 
United States. Analyses and Analytical 
Methods. BuMines Bull. 486, 1951, 
141 pp. 

2. Boone, W. J., Jr. Helium-Bearing 
Natural Gases of the United States. 
Analyses and Analytical Methods. Supple- 
ment to Bulletin 486. BuMines Bull. 576, 
1958, 117 pp. 

3. Munnerlyn, R. D. , and R. D. Mil- 
ler. Helium-Bearing Natural Gases of the 
United States, Analyses. Second Supple- 
ment to Bulletin 486. BuMines Bull. 617, 
1963, 93 pp. 

4. Miller, R. D. , and G. P. Norrell. 
Analyses of Natural Gases of the United 
States, 1961. BuMines IC 8221, 1964, 
148 pp. 

5. . Analyses of Natural Gases 

of the United States, 1962. BuMines 
IC 8239, 1964, 120 pp. 

6. . Analyses of Natural Gases 

of the United States, 1963. BuMines 
IC 8241, 1965, 102 pp. 

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3Sf 



^e 



9 



•■^•f 



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